1. Initially, we place 2
mol of A and 4 mol of B in a 0.5 L flask. At equilibrium, the flask contains
0.3 mol of C. Determine the value of K.
2. We place 1 mol of A
and 1.5 mol of B in a 250 mL container. We find that, at equilibrium, we have
0.5 mol of B. Calculate the value of K.
3. A system is
represented by the following equation:
At equilibrium, [C]=0.6 M. Calculate
the value of K if initially 1 mol of A and 2 mol of B were placed in a 1 L
flask.
4. In a 500 mL flask, we
put 6 mol of A, 6 mol of B, 4 moles of C and 9 mol of D. The value of K is
17.3.
Is the system in equilibrium? If not,
in which direction will the reaction proceed to attain equilibrium?
5. A 100 mL container is
filled with 0.01 mol of A2B3. At equilibrium, it also
contains 0.006 mol of B. Find the value of K.
6. You are given the
following equation:
You fill a 1 L flask with 0.20 mol of
A2B. 0.5% of this substance dissociates. What is the value of K?
7. 5.6 x 10-6 mol
of A and 5 x 10-5 mol of B are mixed in a 200 mL flask. The
system is represented by the equation:
At equilibrium, there is 4.8 x 10-5 mol
of B. Calculate the value of the equilibrium constant.
8. K = 1.7 x 10-10 for
the following system, which represents the dissolving of silver chloride:
What will the concentration of Ag+ be
at equilibrium (in M)?
9. You work with the
following system:
At, equilibrium, [Y]=3[X]. If K=10,
calculate the [Y] at equilibrium.
10. A chemical system
within a sealed 1 L reaction vessel is described by the following reversible
reaction equation:
2H2S(g) <-->2H2(g) +
S2(g)
If the equilibrium constant is 0.000
004 200 at 1103 K find:
11. the reaction quotient
initially.
12. the order of
concentration of all three components at equilibrium (greatest concentration to
lowest) without using calculations.
13. what the size of the
reaction quotient indicates regarding the extent of the forward reaction.
14. the equilibrium
concentration of sulphur gas if 0.070 mol of hydrogen sulphide gas is initially
placed in the vessel.
Note: for part d you may make the
simplifying assumption that the amount of hydrogen sulphide gas reacted is
extremely small in relation to the initial amount of hydrogen sulphide gas—this
will allow you to avoid a quadratic expression in the denominator of the
reaction quotient by disregarding one term).
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